海洋表层沉积物中金属镉的来源解析     

谭赛章  杨涛  可愚  刘材材  张昊飞 《海洋通报》2019,38(6):683-689

利用2015年8月份对长江口及其邻近海域表层沉积物的监测数据,基于主成分分析/绝对主成分分数(PCA/APCS)受体模型定量解析了重金属元素镉(Cd)的可能来源,并结合地统计学插值了Cd的源贡献量的空间分布状况,结果表明沉积物中镉污染主要存在3个可能来源,源头及贡献率分别为工业污染(18.8%)、陆地径流输入(66.0%)、生物活动等自然因素(13.6%),并且各个源头贡献量具有不同的空间分布状况,其中工业污染的高值区主要集中在靠近陆地区域,陆地径流输入的分布呈现由近岸向外海逐减降低的特征,生物活动等自然因素的高值区主要集中在远离陆地的外海区域。  相似文献   

抗旱保水剂膨润土-聚丙烯酸盐吸水树脂研究   总被引：2，自引：0，他引：2  

刘建朝  左可胜  李绍卿  李剑敏 《地球科学与环境学报》2005,27(4):58-62

利用丙烯酸盐在蒙脱石层间进行原位聚合，研究开发一种适用于农林业的抗旱保水剂。实验结果表明：聚合产物的综合性能较为理想，吸水树脂的保水作用主要体现在能够吸收大量的水，并且在压力下不脱水。  相似文献   

Cd2+在甘肃靖远坡缕石粘土上的吸附作用研究   总被引：2，自引：1，他引：1  

郝艳玲  范福海 《岩石矿物学杂志》2008,27(6):567-571

以提纯后的甘肃靖远坡缕石粘土作吸附剂,常温下对水中Cd2 进行吸附实验,考察了吸附时间、吸附剂用量、振荡速率及pH值对吸附效果的影响,并对吸附动力学过程和吸附平衡进行了探讨.XRD和红外光谱分析结果显示,原矿在提纯后杂质石英被有效分离,得到了坡缕石含量较高的提纯样品.吸附实验结果显示,约60 min吸附反应可达平衡;pH值对吸附效果有显著影响,吸附率随pH值的升高而增加,当平衡溶液pH>8时吸附率超过99%;吸附过程与pseudo-second-order Lagergren动力学模型方程有较好的一致性,吸附平衡同时符合Langmuir和Freundlich等温吸附模型,由Langmuir方程得到饱和吸附量为31.65 mg/g.  相似文献   

乌兰图嘎超大型锗矿床含锗煤的矿物学   总被引：2，自引：0，他引：2  

张琦  戚华文  胡瑞忠  王小飞 《矿物学报》2008,28(4)

内蒙古乌兰图嘎锗矿是我国近年来发现的产在煤层中的超大型锗矿床,锗金属储量达1600 t。以乌兰图嘎超大型锗矿床的含锗煤为研究对象,利用X射线衍射(XRD)、带能谱的扫描电镜(SEM-EDX)和电子探针(EPMA)详细研究了乌兰图嘎含锗煤及其同时代的红旗煤矿无矿煤的矿物学特征。分析结果表明,乌兰图嘎含锗煤中的主要矿物包括石英、蒙脱石;次要矿物包括长石、高岭石、伊利石;另含少量三水铝石、角闪石、叶蜡石、石膏、绿泥石、锐钛矿、黄铁矿、方解石、白云石和草酸钙石;微量的锆石、闪锌矿、白钨矿、重晶石、黄铜矿、卤化物、磷酸盐以及含Pb、Bi、Cr、As和Sb矿物。未发现含锗矿物。推测含锗煤中的锗可能主要呈有机结合,而Ba、Zn、Ti、W、Pb、Bi、Cr、Fe、As、Zr、Sb、Cu和REE可能主要与矿物相结合。此外,首次在乌兰图嘎含锗煤及红旗煤矿无矿煤中发现含银颗粒或自然银,推测胜利煤田的褐煤可能有相当规模的Ag矿化。  相似文献   

Local Distribution and Seasonal Variation of Fe, Pb, Zn, Cu, Cd, Na, K, Ca, and Mg Concentrations in the Seagrass Cymodocea nodosa (ucria) Aschers. in the Antikyra Gulf, Greece     

P. Malea  S. Haritonidis 《Marine Ecology》1995,16(1):41-56

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Lower Cd/P ratio in settling particles than in surface seawater in the Okinawa Trough     

Kazuo Abe  Kazuo Iseki  Kazumaro Okamura  Yoko Kiyomoto 《Journal of Oceanography》2006,62(5):745-752

The characteristics of the ratios between cadmium (Cd) and phosphorus (P) in settling particles collected from the Okinawa Trough in the East China Sea were examined using a sediment trap, moored at a depth of 811 m for one year. The Cd/P ratios varied within a narrow range throughout the year, in spite of the large seasonal change in the total dry mass, Cd, and P fluxes. The average Cd/P ratio of settling particles was 0.062 (nmol/μmol), which was obviously lower than that of surface seawater around the study site (0.16). This lower ratio in the Okinawa Trough particles collected using the 811 m-moored trap certainly reflected the mixture of biologically produced organic matter around the study site and other components that were mainly transported as lateral flux from the shelf edge and slope area of the East China Sea.  相似文献   

Relationship between Cd and PO4 in the Subtropical Sea near the Ryukyu Islands     

Kazuo Abe 《Journal of Oceanography》2002,58(4):577-588

The relationship between dissolved cadmium (Cd) and phosphate (PO₄) was examined at three stations in the subtropical area near the Ryukyu Islands in May 1999. Preformed PO₄ was obtained using the Redfield ratio in order to separate the surface water and the other layers in this study area. Almost 0 μM (−0.043 μM to 0.094 μM) was estimated in the layers above 300 m and 250 m at Sts. 1 and 3 and at St. 2, respectively. Up to these depths, water was considered to be uniform, and these layers were defined as the surface water in this study area. In the surface water, the slopes of the regression lines of the Cd-PO₄ plot were 0.162, 0.156, and 0.226 (nM/μM) at Sts. 1, 2, and 3, respectively, and these values were much closer to the estimated regenerated ratio of Cd to PO₄ from the Apparent Oxygen Utilization (AOU)-Cd/PO₄ plots, which was 0.197 (nM/μM) in this study area. Below surface layers, the slopes of the Cd-PO₄ plot changed to 0.371, 0.352, and 0.362 (nM//μM) at Sts. 1, 2, and 3, respectively. In the relationships between Cd and PO₄, clear deviations or kinks were observed at three stations at a PO₄ concentration of approximately 0.2 μM in the plot, which was attributable to the discontinuity of surface water and the other layers across the North Pacific subtropical mode water. In studies of the interaction between surface water and biogenic particles concerning the Cd/PO₄ ratio, separate analyses of seawater (surface water and the other layers) should be carried out to obtain the individual surface water ratio because the Cd/PO₄ ratio in the surface water is expected to differ from that of the underlying water. Furthermore, the biological fractionation of these constituents is based on the surface water ratio. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

闽江口段溶解态镉,铅和铜的收支平衡     

林峰  许清辉 《台湾海峡》1990,9(3):251-255

利用潮输沙量的计算方法,估算了闽江口入海口内3个断面所包围区域溶解态镉、铅和铜的收支平衡,从而研究了这些重金属的河口行为。  相似文献   

Chemistry of marine resources-ⅩⅨ. The molecule design and synthesis of crow-link type alkyd resin and its enrichment behaviour for potassium ion in sea water     

Sun Yushan  Feng Fei  Sun Hanzhang  Peng Qiqiang  Xia Zongfeng  Wang Wei 《海洋学报(英文版)》1994,13(3):377-388

This paper first presents the molecule design and synthesis of crown-link type alkyd resin,and its enrichment behaviour for potassium ion in low concentration solution and sea water.On the basis of some theory concepts of Host-Guest chemistry developed in recent years,we have designed and synthesized a new polymer enrichment agent of crow-link resin for potassiumion,i.e.,polymacrocyclic ether bislactone of diethylene glycolpyromyllitic acid(briefly called crown-link type alkyd resin or PBL resin).The yield was about 97.4%,almost quantitatively.  相似文献   

干旱区绿洲土壤共存重金属元素形态变化及生物有效性实验分析——以Cd、Zn、Ni元素为例   总被引：3，自引：0，他引：3  

赵转军  南忠仁  王胜利  刘晓文  陶燕 《地球科学进展》2008,23(11):1194-1200

采用盆栽试验,初步研究了干旱区绿洲土壤—胡萝卜系统中镉、锌、镍3种重金属的形态变化特征及其生物有效性问题。结果表明:供试绿洲土壤原状土中,Cd、Zn、Ni均以稳定的残渣态形式存在,而处理土壤中重金属被钝化的量有限,Cd的存在形式主要以碳酸盐态为主,Zn、Ni则主要以铁锰氧化态为主;3种元素的活性大小依次为Cd>Ni>Zn。根据回归分析,元素Zn对胡萝卜块茎和茎叶吸收Zn量贡献最大的分别是Zn的碳酸盐结合态和铁锰氧化态;元素Ni对胡萝卜各部位吸收贡献最大的均为Ni的铁锰氧化态。  相似文献